Guidelines

Can rates of reaction be positive or negative?

Can rates of reaction be positive or negative?

The rate of a reaction is always positive. A negative sign is present to indicate that the reactant concentration is decreasing. The IUPAC recommends that the unit of time should always be the second.

Can the rate order be negative?

Re: Negative Order A reaction rate can have a negative partial order with respect to a substance. For example, the conversion of ozone (O3) to oxygen follows the rate equation (rate = k[O3]^2/[O2]) in an excess of oxygen. This corresponds to second order in ozone and order (-1) with respect to oxygen.

Can K be negative equilibrium constant?

8.2. 1 : The equilibrium constant Kc is a constant which represents how far the reaction will proceed at a given temperature. 8.2. When much less than 1 (Kc can never be negative…so when it is close to zero) the reaction hardly occurs at all.

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Can rates be negative physics?

Most certainly! When the instantaneous rate of change of a function at a given point is negative, it simply means that the function is decreasing at that point. For a line, the rate of change at any given point is simply m. This can also be seen in physics.

Why the rate of reaction is always positive?

The concentration of a reactantalways decreases with time, so and are both negative. Sincenegative rates do not make much sense, rates expressed in terms of a reactant concentration are alwayspreceded by a minus sign to make the rate come out positive.

Can a rate be negative in math?

Rates of change can be positive or negative. This corresponds to an increase or decrease in the y -value between the two data points.

Can rate law exponents be negative?

The exponents m, n, and p are usually positive integers (although it is possible for them to be fractions or negative numbers).

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What is the rate constant in chemistry?

proportionality constant
The rate constant, or the specific rate constant, is the proportionality constant in the equation that expresses the relationship between the rate of a chemical reaction and the concentrations of the reacting substances.

Can the equilibrium constant be zero?

The equilibrium constant cannot be 0. This is because this implies that the concentration of products is equal to 0 at equilibrium.

How do you find the equilibrium constant for a reverse reaction?

The equilibrium expression written for a reaction written in the reverse direction is the reciprocal of the one for the forward reaction. K’ is the constant for the reverse reaction and K is that of the forward reaction. N2O4(g) at 100o C?…

Equation Equilibrium Constant
N2(g) + O2(g) NO2(g) Kc = 4.1 x 10-9

Why does the rate of reaction not remain constant throughout the reaction process?

The rate of a reaction does not remain uniform throughout the reaction because it depends on concentration which changes with passage of time.

Can the rate of a chemical reaction be negative?

The big companies don’t want you to know his secrets. Positive and negative rates are conventionally used to signify the formation or consumption, respectively, of a species. Rates are not negative in an absolute sense but can be in relation to other species. Can rate constant of a chemical reaction be negative?

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Can the rate constant be negative?

CHEMISTRY COMMUNITY. Re: Negative Rate Constant? Rate constant k should always be positive. From the Arrhenius Equation, we know k = A x exp (-Ea/RT). “A” (frequency factor) will always be positive because (according to Google) there are no experimental cases where A is negative, and mathematically exp (-Ea/RT) can never be negative.

Can the rate constant of an exponential reaction be negative?

Given that the pre-exponential factor of the Arrhenius equation is always positive (otherwise, you would potentially have a rate constant of 0, meaning the reaction never occurs), the rate constant is never negative.

What is the rate constant of a reaction?

Updated January 02, 2021 The rate constant is a proportionality factor in the rate law of chemical kinetics that relates the molar concentration of reactants to reaction rate. It is also known as the reaction rate constant or reaction rate coefficient and is indicated in an equation by the letter k. Key Takeaways: Rate Constant