Guidelines

What is the oxidation number for chlorine?

What is the oxidation number for chlorine?

The oxidation number of chlorine are +1,+3,+5,+7 and -1. However, for Chlorine gas, the oxidation number (Cl2) is zero. Chlorine will have different oxidation numbers in oxide forms.

What determines the oxidation number of an element?

Oxidation number is the charge left on the central atom or element, when all the bonding pairs of electrons are removed, with the charge going to the central atom.

What is an oxidation number and how is it determined?

The oxidation number of a monatomic ion equals the charge of the ion. The oxidation number of H is +1, but it is -1 in when combined with less electronegative elements. The oxidation number of O in compounds is usually -2, but it is -1 in peroxides. The oxidation number of a Group 1 element in a compound is +1.

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Why does chlorine have so many oxidation states?

For example, Chlorine can have a +7 oxidation number because its electron configuration ends with 3s^2,3p^5 so if it lost those 7 electrons in the n=3 subshell it would have a completely filled n=2 subshell, or the same electron configuration as Neon.

How are oxidation states assigned?

Rules for Assigning Oxidation Numbers

  1. The convention is that the cation is written first in a formula, followed by the anion.
  2. The oxidation number of a free element is always 0.
  3. The oxidation number of a monatomic ion equals the charge of the ion.
  4. The usual oxidation number of hydrogen is +1.

Does chlorine have oxidation?

Chlorine’s usual oxidation state is -1. But in compounds with oxygen and fluorine chlorine can exibit positive oxidation states. Chlorine has a high electronegativity, meaning that chlorine is good at attracting electrons in a molecular orbital (a bond).

What is more likely oxidation state of chlorine?

As another difference, chlorine has a significant chemistry in positive oxidation states while fluorine does not. Chlorination often leads to higher oxidation states than bromination or iodination but lower oxidation states than fluorination. Chlorine tends to react with compounds including M-M, M-H, or M-C bonds to form M-Cl bonds.

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How to find oxidation number?

Any free element has an oxidation number equal to zero.

  • For monoatomic ions,the oxidation number always has the same value as the net charge corresponding to the ion.
  • The hydrogen atom (H) exhibits an oxidation state of+1. However,when bonded with an element with less electronegativity than it,it exhibits an oxidation number of -1.
  • Oxygen has an oxidation of -2 in most of its compounds. However,in the case of peroxides,the oxidation number corresponding to oxygen is -1.
  • All alkali metals (group 1 elements) have an oxidation state of+1 in their compounds.
  • All alkaline earth metals (group 2 elements) exhibit an oxidation state of+2 in their compounds.
  • In the compounds made up of two elements,a halogen (group 17 elements) have an oxidation number of -1 assigned to them.
  • In the case of neutral compounds,the sum of all the oxidation numbers of the constituent atoms totals to zero.
  • When polyatomic ions are considered,the sum of all the oxidation numbers of the atoms that constitute them equals the net charge of the polyatomic ion.
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    What is the electronegativity value of chlorine?

    The first scale of electronegativity was developed by Linus Pauling and on his scale chlorine has a value of 3.16 on a scale running from from about 0.7 (an estimate for francium ) to 2.20 (for hydrogen) to 3.98 (fluorine).

    How do you find the oxidation state?

    The oxidation state is the positive or negative number of an atom in a compound, which may be found by comparing the numbers of electrons shared by the cation and anion in the compound needed to balance each other’s charge. The cation has a positive oxidation state, while the anion has a negative oxidation state.